黄、渤海无机氮的收支模式初探   总被引：8，自引：1，他引：8  

王保栋  单宝田  战闰  藏家业 《海洋科学》2002,26(2):33-36

根据黄、渤海无机氮的收支状况，首次提出了黄、渤海无机氮的稳态收支模式。模式研究结果表明，大气沉降、陆源输入和海底输入的无机氮通量分别占黄、渤海无机氮浮游植物总需求量的3%、4%和12%。无机氮的外部输入约占总需求量的1/5，其他部分则由水柱中的内部再循环（再生）供给。  相似文献   

Measurement of ²²⁴Ra, ²²⁶Ra and ²²⁸Ra in seawater using Mn-fiber adsorption-γ spectrum method   总被引：2，自引：1，他引：2  

Liu Guangshan  Huang Yipu  Chen Xinbao 《海洋学报(英文版)》2000,19(2):19-27

I~IOXThe half-lives of natural radioactive nuclides "'Ra, 226Ra and 228Ra are 3. 66 d, 5. 76 a,1600 a respectively, hence, the marine process with various time scales can be researched by taking these nuclides as tracers. Because these nuclides can be determined by measuring them or theirdaughters' a,g, y-rays, they have been applied extensively in oceanography research. Huang(1996), Huang et al. (1996 a,b) and Chen (1996) have given reviews on it.Since the contents of "'Ra, 226Ra and 228…  相似文献   

Sources and distribution of organic matter in a river-dominated estuary (Winyah Bay, SC, USA)   总被引：12，自引：0，他引：12  

Miguel A. Goi  Maria J. Teixeira  David W. Perkey 《Estuarine, Coastal and Shelf Science》2003,57(5-6):1023-1048

The sources and distribution of organic matter (OM) in surface waters and sediments from Winyah Bay (South Carolina, USA) were investigated using a variety of analytical techniques, including elemental, stable isotope and organic biomarker analyses. Several locations along the estuary salinity gradient were sampled during four different periods of contrasting river discharge and tidal range. The dissolved organic carbon (DOC) concentrations of surface waters ranged from 7 mg l⁻¹ in the lower bay stations closest to the ocean to 20 mg l⁻¹ in the river and upper bay samples. There was a general linear relationship between DOC concentrations and salinity in three of the four sampling periods. In contrast, particulate organic carbon (POC) concentrations were significantly lower (0.1–3 mg l⁻¹) and showed no relationship with salinity. The high molecular weight dissolved OM (HMW DOM) isolated from selected water samples collected along the bay displayed atomic carbon:nitrogen ratios ([C/N]a) and stable carbon isotopic compositions of organic carbon (δ¹³C_OC) that ranged from 10 to 30 and from −28 to −25‰, respectively. Combined, such compositions indicate that in most HMW DOM samples, the majority of the OM originates from terrigenous sources, with smaller contributions from riverine and estuarine phytoplankton. In contrast, the [C/N]a ratios of particulate OM (POM) samples varied significantly among the collection periods, ranging from low values of 5 to high values of >20. Overall, the trends in [C/N]a ratios indicated that algal sources of POM were most important during the early and late summer, whereas terrigenous sources dominated in the winter and early spring.In Winyah Bay bottom sediments, the concentrations of the mineral-associated OM were positively correlated with sediment surface area. The [C/N]a ratios and δ¹³C_OC compositions of the bulk sedimentary OM ranged from 5 to 45 and from −28 to −23‰, respectively. These compositions were consistent with predominant contributions of terrigenous sources and lesser (but significant) inputs of freshwater, estuarine and marine phytoplankton. The highest terrigenous contents were found in sediments from the river and upper bay sites, with smaller contributions to the lower parts of the estuary. The yields of lignin-derived CuO oxidation products from Winyah Bay sediments indicated that the terrigenous OM in these samples was composed of variable mixtures of relatively fresh vascular plant detritus and moderately altered soil OM. Based on the lignin phenol compositions, most of this material appeared to be derived from angiosperm and gymnosperm vascular plant sources similar to those found in the upland coastal forests in this region. A few samples displayed lignin compositions that suggested a more significant contribution from marsh C₃ grasses. However, there was no evidence of inputs of Spartina alterniflora (a C₄ grass) remains from the salt marshes that surround the lower sections of Winyah Bay.  相似文献   

九龙江河口区表层水铀同位素的粒级分布          下载免费PDF全文

吕娥  张磊  陈敏  邱雨生  邢娜  杨伟锋  李艳平  黄奕普 《海洋学报》2007,29(4):59-68

利用微滤和超滤技术研究了九龙江河口区表层水中铀及其同位素组成的粒级分布和地球化学行为.结果表明,溶解态(<0.4μm)中低分子量组分(<10 000 u)占主要份额,胶体态(10 000 u~0.4μm)238U所占比例不足1%,且随盐度的增加其所占份额逐渐降低.溶解态、低分子量组分和胶体态238U的比活度与盐度之间存在良好的线性正相关关系,证实它们在九龙江河口区呈现保守行为.在颗粒态(>0.4μm)中,各粒级组分238U所占份额主要受控于相应颗粒物的浓度,在盐度小于20的区域,各粒级颗粒组分238U占颗粒态的份额有如下变化次序:10~53μm>2~10μm>0.4~2μm>大于53μm,而在盐度大于30的近外海站位,该次序发生一些变化:0.4~2μm>10~53μm>2~10μm>大于53μm,最小粒级颗粒组分238U的贡献有所增加,反映了自生铀贡献的加强.九龙江河口区表层水中溶解态(包括低分子量组分和胶体态)的234U/238U)_A.R.均大于1,显示出234U过剩的特征,而各粒级颗粒组分中的234U/238U)_A.R.则接近于平衡值(1.0).这一现象与陆地岩石风化过程中水体对铀的淋滤释出量及234U的优先浸出有关.对232Th/238U质量比的研究显示,溶解态及其所包括的低分子量组分和胶体态的232Th/238U质量比均小于1,而颗粒态及其所包括的4个粒级组分中的232Th/238U质量比均大于1,反映了向外海输送过程中铀、钍地球化学行为的差异.  相似文献   

Determination of phospholipid fatty acid structures and stable carbon isotope compositions of deep-sea sediments of the Northwest Pacific, ODP site 1179   总被引：1，自引：0，他引：1  

Christopher T. Mills  Robert F. Dias  Dennis Graham  Kevin W. Mandernack   《Marine Chemistry》2006,98(2-4):197-209

Sediment samples ranging from 0.05 to 278 m below sea floor (mbsf) at a Northwest Pacific deep-water (5564 mbsl) site (ODP Leg 191, Site 1179) were analyzed for phospholipid fatty acids (PLFAs). Total PLFA concentrations decreased by a factor of three over the first meter of sediment and then decreased at a slower rate to approximately 30 mbsf. The sharp decrease over the first meter corresponds to the depth of nitrate and Mn(IV) reduction as indicated by pore water chemistry. PLFA-based cell numbers at site 1179 had a similar depth profile as that for Acridine orange direct cell counts previously made on ODP site 1149 sediments which have a similar water depth and lithology. The mole percentage of straight chain saturated PLFAs increases with depth, with a large shift between the 0.95 and 3.95 mbsf samples. PLFA stable carbon isotope ratios were determined for sediments from 0.05 to 4.53 mbsf and showed a general trend toward more depleted δ¹³C values with depth. Both of these observations may indicate a shift in the bacterial community with depth across the different redox zones inferred from pore water chemistry data. The PLFA 10me16:0, which has been attributed to the bacterial genera Desulfobacter in many marine sediments, showed the greatest isotopic depletion, decreasing from − 20 to − 35‰ over the first meter of sediment. Pore water chemistry suggested that sulfate reduction was absent or minimal over this same sediment interval. However, 10me16:0 has been shown to be produced by recently discovered anaerobic ammonium oxidizing (anammox) bacteria which are known chemoautotrophs. The increasing depletion in δ¹³C of 10me16:0 with the unusually lower concentration of ammonium and linear decrease of nitrate concentration is consistent with a scenario of anammox bacteria mediating the oxidation of ammonium via nitrite, an intermediate of nitrate reduction.  相似文献   

Differences in ratios of stable isotopes of nitrogen in long-finned pilot whales (Globicephala melas) in the western and eastern North Atlantic   总被引：1，自引：0，他引：1  

Abend  Alan G.; Smith  Tim D. 《ICES Journal of Marine Science》1995,52(5):837-841

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赤潮发生机理研究──海洋原甲藻的氮营养生理特征   总被引：17，自引：1，他引：17  

黄晓航  史冬梅  张京浦  刘海航  吴超元 《海洋与湖沼》1997,28(1):33-38

于１９９１年１月－１９９１年１２月，以不同浓度的硝态氮（２０，６０，２００，６００μｍｏｌ／Ｌ）研究对赤潮生物海洋原甲藻的生长和生化组成的影响，及其营养生理特性，结果表明，在氮浓度为２００和６００μｍｏｌ／Ｌ时，表现光合作用强，细胞生长快，指数生长期长，叶绿素含量高，提示了由原甲藻爆发引起的赤潮与海洋富营养化有直接关系，结果还表明，海洋原甲藻可以累积蛋白质和碳水化合物，当外界氮源不能满足生长需要时  相似文献   

Geochemistry of trace elements and Sr-Nd isotopes of foraminifera shell from the Okinawa Trough   总被引：1，自引：0，他引：1  

Meng Xianwei  Du Dewen  Cheng Zhenbo 《海洋学报(英文版)》2001,20(1):95-103

ＩＮＴＲＯＤＵＣＴＩＯＮＰｒｏｖｅｎａｎｃｅｏｆｍａｒｉｎｅｓｅｄｉｍｅｎｔｓｈａｓａｌｗａｙｓｂｅｅｎａｆｏｃｕｓｅｄｐｒｏｂｌｅｍｉｎｍａｒｉｎｅｓｅｄｉｍｅｎｔｇｅ ｏｌｏｇｙ.Ｒｅｃｏｇｎｉｔｉｏｎｏｆｅｎｄｍｅｍｂｅｒｓａｎｄｅｓｔｉｍａｔｉｏｎｏｆｔｈｅｉｒｒｅｌａｔｉｖｅｐｒｏｐｏｒｔｉｏｎｓｆｒｏｍｍｉｘｅｄｓｅｄｉｍｅｎｔｓｈａｖｅｂｅｅｎａｋｅｙｃｏｎｔｅｎｔｉｎｔｈｅｓｔｕｄｙｏｆｐｒｏｖｅｎａｎｃｅ .Ｆｏｒｔｈｉｓａｉｍ ,ｉｔｉｓｎｅｃｅｓｓａｒｙｔｏｓｅｌｅｃｔｅｎｄｍｅ…  相似文献   

Factors influencing the oxidation,reduction, methylation and demethylation of mercury species in coastal waters     

Lindsay Whalin  Eun-Hee Kim  Robert Mason 《Marine Chemistry》2007

The objective of this study was to examine the redox reactions and other transformations of mercury (Hg) species in surface waters, and the factors determining the rates of these reactions. For the redox studies completed at the Chesapeake Biological Laboratory (CBL), two isotopes (¹⁹⁹Hg^II and ²⁰²Hg⁰) were added into different types of filtered water (fresh to seawater) to examine the oxidation and reduction reactions. Further studies of both the redox reactions and methylation/demethylation reactions of Hg were conducted with unfiltered water on board research vessels during cruises in May and July 2005 on the Chesapeake Bay and shelf. While CH₃¹⁹⁹Hg^II was added to allow the examination of demethylation, ²⁰¹Hg^II was used to examine both reduction and methylation, and ²⁰²Hg⁰ was used to examine oxidation. Overall, the results showed that both Hg oxidation and reduction were simultaneously occurring and were photochemically mediated in the waters investigated. In contrast to the previously assumed “unreactive” nature of Hg⁰, the studies found that the magnitude of the rate constant for Hg⁰ oxidation was greater than that for reduction, indicating its importance in estuarine and coastal waters. In addition, both experiments at CBL and on board ship showed that Hg^II reduction was similar in magnitude, suggesting that biotic processes were relatively unimportant. While no measurable methylation occurred during the incubation period during the on board studies, concentration of CH₃¹⁹⁹Hg^II decreased over the time during the experiments. It appeared that the demethylation processes were not dominantly photochemically driven, but could be microbially mediated. Further studies are needed in order to help better understand Hg redox and transformations in natural water systems.  相似文献   

水中总氮的紫外分光光度分析法     

刘新 《海洋湖沼通报》1993,(3):60-66

本文采取K_2 S_2O_8氧化法,研究了氧化条件、紫外分光光度法测定总氮的最佳条件以及可能产生的干扰及消除方法。利用本法测定天然水中总氮回收率100±2％,检出限为0.010mg·dm~(-3)。方法快速准确,与Kjedahl法相比可提高工效27倍。  相似文献